Kitui High School emerged top in the 2019 Kenya Certificate of Secondary Education, KCSE, examination in Kitui County. The school had a mean score of 8.5878 (B plain) to take position 44 nationally.
The second and third positions were scooped by Kisasi Boys and Muthale Girls High school; respectively.
Here is a list of the KCSE 2019 best 10 schools in Kitui County:
| Pos in County | School | KCSE 2019 Mean | County | Pos Nationally |
| 1 | Kitui School | 8.5878 | Kitui | 44 |
| 2 | Kisasi Boys | 8.47 | Kitui | 50 |
| 3 | Muthale Girls | 8.102 | Kitui | 69 |
| 4 | St Charles Lwanga | 7.6897 | Kitui | 113 |
| 5 | Matinyani Boys | 7.67 | Kitui | 115 |
| 6 | Kimangao Girls | 7.3267 | Kitui | 140 |
| 7 | Kyamboo Secondary | 7.3 | Kitui | 143 |
| 8 | Ikanga Boys | 7.01 | Kitui | 169 |
| 9 | St Angela’s Girls | 6.99 | Kitui | 176 |
| 10 | Mbitini Girls | 6.97 | Kitui | 180 |
| 11 | Mulango Girls | 6.836 | Kitui | 188 |
| 12 | Chuluni Girls | 6.822 | Kitui | 189 |
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